Trade Name: GULF SILICON-FREE DASHBOARD POLISH
 
1. Product and Company Identification
Trade Name GULF SILICON-FREE DASHBOARD POLISH

Product Code

7903312
Product type and use Dashboard polish
Producer GULF SOUTH EAST EUROPE s.r.l.
Via P Borghi,
1 - 42025 Cavriago (RE)

Phone (Routine)

(++39) 0522 371332
Fax (Routine) (++39) 0522 371633
E-mail montitm@tin.it
Emergency contact numbers of the company and/or of authorized advisory centre
GULF SOUTH EAST EUROPE
Phone (++39) 0385 716105
Fax   (++39) 0385 71453
 
2. Ingredients Composition and Information
Hazardous components conforming to EEC directive 67/548 and corresponding classification.
Components N.67/548/EEC CAS EINECS
50% - 60% heptane [and isomers] 601-008-00-2 142-82-5 205-563-8

Xn Harmful
R38 Irritating to skin
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R65 Harmful: may cause lung damage if swallowed
R67 Vapours may cause drowsiness and dizziness

    

5% - 7% butane

 601-004-00-0 106-97-8 203-448-7
5% - 7% 1,2-dichloropropane 602-020-00-0 78-87-5 201-152-2

Xn Harmful
R20/22 Harmful by inhalation and if swallowed

    
 
3. Hazards Identification
The product catches fire easily, if it is exposed to a ignition source, with a temperature under 21°C, as well.
The product containes a liquefied gas that catches fire with extreme ease, even at temperatures below 0 °C.
If brought into contact with the skin, the product causes appreciable inflammation, with erythema, scabs, and oedema.
Canister under pressure. The container exposed to a temperature > 50°C can deform and explode.
The inhalation in high quantities is asphyxiating.
 
4. First Aid Measures
Contact with skin Immediately take off all contaminated clothing. Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap.
Contact with eyes Wash immediately with water for at least 10 minutes.
Swallowing Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY. A suspension of activated charcoal in water, or liquid paraffin may be administered.
Inhalation Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION.
 
5. Fire Fighting Measures
Recommended extinguishers CO2, Foam, Chemical powders, according to the materials involved in the fire. NEVER USE WATER.
Extinguishers not to be used None in particular. Never use water.
Risks arising from combustion Avoid inhaling the fumes. Combustion may form toxic gas.
Protective equipment Use protection for the respiratory tract. Cool the containers exposed to the fire with water
Explosion Hazard The aerosol container explodes if overheated and can be thrown over a big distance.
 
6. Accidential Release Measures
Measures for personal safety Use a mask, gloves and protective clothing.
Environmental measures Limit leakages with earth or sand. Eliminate all unguarded flames and possible sources of ignition. Do not smoke. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities.
Cleaning methods Rapidly recover the product. To do so, wear a mask and protective clothing. If the product is in a liquid form, stop it from entering the drainage system. Recover the product for re-use if possible, or for elimination. The product might, where appropriate, be absorbed by inert material. After the product has been recovered, rinse the area and materials involved with water.
 
7. Handling and Storage
Handling precautions Container under pressure. Do not perforate, don't burn, don't tamper with the valve, neither after the use. Avoid contact and inhalation of the vapours. See, too, paragraph 8 below. Do not eat or drink while working. Do not smoke while working.
Storage conditions Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight. Keep away from flame and sparks. Avoid accumulating electrostatic charge.
Instructions as regards storage premises: Cool and adequately ventilated. Safe electric system.
 
8. Exposure Control/Personal Protection
Precautionary measures Give adequate ventilation to the premises where the product is stored and/or handled.
Respiratory protection Not needed for normal use.
Protection for hands Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Eye protection Not needed for normal use.
Protection for skin Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Exposure limit(s) (ACGIH) heptane [and isomers]
TLV-TWA: 1640 mg/m3, 400 ppm    TLV-STEL: 2050 mg/m3, 500 ppm
butane
TLV-TWA: 1900 mg/m3, 800 ppm
1,2-dichloropropane
TLV-TWA: 75 ppm    TLV-STEL: 510 mg/m3
 
9. Physical and Chemical Properties
Appearance and colour Liquid paglierino sotto pressione (aerosol)
Odour Caratteristico dell'essenza contenuta
pH N.D.
Melting point N.D.
Boiling point > - 42°C (Propellente)
Flash point inferiore a  - 80°C (Propellente)
Autoignition temperature 400°C (Propellente)
Explosive properties Inf.1,8% Sup.9,5% volvol in aria (Propellente)
Vapour pressure 5,5 bar al caricamento a 20°C
Relative density 0,74 Kg/l (Rif. alla Base)
Solubility in water No
Lipid solubility Yes
 
10. Stability and Reactivity
Stability The containers can explode if overheated to a temperature > 50°C.
Conditions to avoid Avoid the direct exposition under the sun or to a higher temperature of 50°C. Avoid accumulating electrostatic charge.
Substances to avoid Avoid high oxidative products and acid or basic products, which can attack the container. Avoid contact with combustible materials. The product could catch fire.
Hazardous decomposition products None
 
11. Toxicological Information
The concentration of each substance should be borne in mind in assessing the toxicological effects deriving from the preparation. Set out below is the toxicological information relating to the main substances in the preparation.

1,2-dichloropropane

 OBSERVATIONS ON HUMAN SUBJECTS:
Irritant to respiratory tract, eyes and skin: it can cause dermatitis.
It can damage the liver and kidneys and induce narcosis.
Prolonged exposure at sub-narcotic concentrations causes chronic  effects: headache, pronounced irritability, visual disorders and dizziness and, on occasions, loss of weight, apathy and nervous symptoms.
 
12. Ecological Information
Adopt sound working practices, so that the product is not released into the environment.
Components N.67/548/EEC CAS EINECS
50% - 60% heptane [and isomers] 601-008-00-2 142-82-5 205-563-8
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.    
 
13. Disposal Considerations
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force.
 
14. Transport Information
Road (ADR) 2 5°F
UN number UN 1950 AEROSOLS
 
15. Regulatory Information
88/379/EEC (Classification and Labelling)
Symbols

Xi Irritant
F+ Extremely flammable
R Phrases R12 Extremely flammable.
R67 Vapours may cause drowsiness and dizziness.
R38 Irritating to skin.
S Phrases S13 Keep away from food, drink and animal feedingstuffs.
S16 Keep away from sources of ignition - No smoking.
S29 Do not empty into drains.
S33 Take precautionary measures against static discharges.
S43 In case of fire, use... CO2, Foam, Chemical powders, according to the materials involved in the fire. NEVER USE WATER.
S46 If swallowed, seek medical advice immediately and show this container or label.
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
S24 Avoid contact with skin.
S2 Keep out of reach of children.
S37 Wear suitable gloves.
Contents heptane [and isomers]
Warning

Pressurized canister. Protect from sunlight and do not expose to temperatures exceeding 50°C.
Do not pierce or burn even after use. Avoid direct inhalation and sprays into the eyes.
Do not spray on naked flames or any incandescent material. Avoid accumulating electrostatic charge.
Store far from any source of combustion. Do not smoke. Keep out of the reach of the children.
Avoid the execessive or improper use of the product, that can cause possible amasses of inflammable gas in the air.
Operate in an airy, ambient space or air the room immediately after the use. Use the product away from flames, heat sources and electric apparatuses while working.
Presidential Decree D.P.R. 303/56 (Health checks).
Presidential Decree D.P.R. 203/56 (COV).
Where applicable, refer to the following regulatory provisions

Ministerial circulars 46 e 61 (Aromatic amines).
Law 136/83 (Biodegradability of detergents).
Presidential Decree D.P.R. 175/88 (Seveso Directive), Appendices II°, III° e IV°.
Presidential Decree D.P.R. 250/89 (Labelling of detergents).
 
16. Other Information

Main bibliographic sources

 NIOSH - Registry of toxic effects of chemical substances (1983)
I.N.R.S. - Fiche Toxicologique
CESIO - Classification and labelling of anionic, nonionic surfactants (1990)
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.
 
To the best of our knowledge, the information provided in this MSDS document is correct. Access to this information is being provided via the internet too so that it can be made available to as many potential users as possible. We do not assume any liability for consequences of the use of this information since it may be applied under conditions beyond our control or knowledge. Also, it is possible that additional data could be made available after this MSDS was issued. Certain hazards are described herein, however, these may not be the only hazards that exist. All materials may present unknown hazards and should be used with caution.
Customers are encouraged to review this information, follow precautionsl and comply with all applicable laws and regulations regarding the use and disposal of this product. For specific technical data or advice concerning this product as supplied in your country please contact your local sales representative. The final determination of the suitability of any material is the sole responsibility of the user.